DOI:
矿床地质:2012,Vol.>>Issue(5):965-982

新疆准噶尔北缘玉勒肯哈腊苏铜(钼)矿床流体包裹体和稳定同位素研究
中国地质科学院矿产资源研究所 国土资源部成矿作用与资源评价重点实验室, 北京 100037;新疆地质矿产勘查开发局第四地质大队, 新疆 阿勒泰 836500;新疆地质矿产勘查开发局第四地质大队, 新疆 阿勒泰 836500;中国科学院新疆生态与地理研究所 新疆矿产资源研究中心, 新疆 乌鲁木齐 830011;新疆地质矿产勘查开发局第四地质大队, 新疆 阿勒泰 836500;新疆地质矿产勘查开发局第四地质大队, 新疆 阿勒泰 836500;新疆地质矿产勘查开发局第四地质大队, 新疆 阿勒泰 836500;中国地质科学院矿产资源研究所 国土资源部成矿作用与资源评价重点实验室, 北京 100037;中国地质科学院矿产资源研究所 国土资源部成矿作用与资源评价重点实验室, 北京 100037
Fluid inclusion and stable isotope study of Yulekenhalasu copper-(molybdenum) deposit in northern margin of Junggar, Xinjiang
YANG FuQuan,LIU GuoRen,QIN JiHua,ZHANG ZhiXin,LIU ZhenJiang,ZHANG LiWu,WEI GuangZhi,LIU Feng,GENG XinXia
(MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, CAGS, Beijing 100037, China;No.4 Geological Party of Xinjiang Bureau of Geology and Mineral Exploration and Development, Altay 836500, Xinjiang, China;Xinjiang Institute of Ecology and Geography, Chinese Academy of Sciences Xinjiang Research Center for Mineral Resources, Urumqi 830011, Xinjiang, China)
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投稿时间:2012-08-12   修订日期:2012-08-20     
中文摘要:玉勒肯哈腊苏中型斑岩型铜(钼)矿主要赋存在闪长玢岩中,有少量矿化产在北塔山组火山岩及似斑状黑云母石英二长岩中。矿化呈细脉状、细脉-浸染状和浸染状。围岩蚀变主要为钾化、硅化、绢云母化、石膏化、磁铁矿化、绿泥石化、绿帘石化。矿床的形成经历了斑岩期、剪切变形期和表生期,铜和钼矿化主要形成于斑岩期的硫化物-钾硅酸盐阶段和辉钼矿阶段。石英和方解石中的流体包裹体可划分为H2O-NaCl型和H2O-CO2(±CH4/N2)-NaCl型。硫化物-钾硅酸盐阶段的成矿温度为141~500℃,主要集中在200~340℃;流体的w(NaCleq) 为2.96%~14.97%;流体的密度为0.60~0.98 g/cm3。碳酸盐阶段的流体以中-低温度(140~320℃)和低盐度〔w(NaCleq) 为2.74%~10.61%〕为特征。硫化物的δ34S值集中于-4.5‰~-0.1‰,峰值为-3.5‰,表明硫来自深源岩浆。石英和方解石的δ18OSMOW值为9.1‰~13.2‰,δ18OH2O值为2.05‰~6.28‰,δD值为-120‰~-97‰,表明主成矿阶段的成矿流体主要是岩浆水,混合有大气降水;碳酸盐阶段的流体主要为大气降水,混合有岩浆水。成矿时代为中泥盆世〔(373.9±2.2 Ma)〕,成矿作用与闪长玢岩的侵入有关。温度和压力的降低导致流体沸腾,同时,水-岩交换反应、流体成分的改变等在铜钼成矿过程中起着主导作用。
Abstract:The Yulekenhalasu medium-size porphyry copper-(molybdenum) deposit occurs in the diorite porphyry, with some mineralization also observed in the porphyroid biotite quartz monzonite and volcanic rocks of the Beitashan Formation. Mineralization occurs as veinlets, veinlet-disseminations and stockworks. Wall-rock alteration is well developed, and mainly comprises K-feldspathization, biotitization, quartzification, sericitization, magnetitization, gypsification, chloritization, and epidotization. According to cutting relationships of the ore veins, mineral assemblages, paragenetic sequence and ore fabrics, the ore-forming process can be divided into three metallogenic periods: porphyry, shear deformation and supergene periods. The sulfides-K-silicate stage and the molybdenite stage in the porphyry period constituted the main stages for copper mineralization and molybdenum mineralization, respectively. Two types of fluid inclusions, namely H2O-NaCl and H2O-CO2(±CH4/N2)-NaCl types, have been recognized in quartz and calcite. Homogenization temperatures of fluid inclusions in the sulfides-K-silicate stage vary from 141℃ to 500℃, concentrated from 200℃ to 340℃. Salinity w(NaCleq) ranges from 2.96% to 14.97%. Ore fluid densities range from 0.60 to 0.98 g/cm3. Fluids of the carbonate stage are characterized by medium-low temperatures (140℃ to 320℃) and low salinities (2.74% to 10.61%). δ34S values of sulfides associated with mineralization range from -4.5‰ to -0.1‰, with the peak being -3.5‰, indicating that sulfur was derived from deep-seated magma. δ18OSMOW values of quartz and calcite range from 9.1‰ to 13.2‰, with the corresponding δ18OH2O values between -2.05‰ and 6.28‰, and δD values of fluid inclusions vary between -120‰ and -97‰. The combined isotopic data imply that the ore-forming fluids of the sulfides-K-silicate stage in the Yulekenhalasu Cu-(Mo) deposit were mainly derived from magmatic fluids, with a minor part from the meteoric water, and the fluids of the carbonate stage were mainly derived from the meteoric water, with a minor part from magmatic fluids. Cu-(Mo) mineralization in Yulekenhalasu took place in Middle Devonian 〔(373.9±2.2) Ma〕, related to the diorite porphyry. The decrease of temperature and pressure, the boiling of local ore-forming fluid, the water-rock exchange, and the compositional variation of ore fluids played important roles in ore-forming processes of the Cu-(Mo) ore bodies.
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中图分类号:P618.41;P618.65     
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基金项目:本文得到国家自然科学基金项目(编号: 40972069)和国家重点基础研究发展计划项目(编号: 2007CB411302)联合资助
引用文本:
杨富全,刘国仁,秦纪华,张志欣,刘振江,张立武,魏广智,刘锋,耿新霞.2012.新疆准噶尔北缘玉勒肯哈腊苏铜(钼)矿床流体包裹体和稳定同位素研究[J].矿床地质,31(5):965~982
YANG FuQuan,LIU GuoRen,QIN JiHua,ZHANG ZhiXin,LIU ZhenJiang,ZHANG LiWu,WEI GuangZhi,LIU Feng,GENG XinXia.2012.Fluid inclusion and stable isotope study of Yulekenhalasu copper-(molybdenum) deposit in northern margin of Junggar, Xinjiang[J].Mineral Deposits31(5):965~982
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