德兴铜厂斑岩铜(钼金)矿床蚀变-矿化系统流体演化:H-O同位素制约
Received:April 26, 2012  Revised:June 10, 2012  点此下载全文
引用本文:PAN XiaoFei,SONG YuCai,LI ZhenQing,HU BaoGen,ZHU XiaoYun,WANG ZengKe,YANG Dan,ZHANG TianFu,LI Yan.2012.Restriction of H-O isotopes for alteration and mineralization system of Tongchang Cu (-Mo-Au) porphyric deposit, Jiangxi Province[J].Mineral Deposits,31(4):850~860
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Author NameAffiliation
PAN XiaoFei Institute of Geology, CAGS, Beijing 100037, China 
SONG YuCai Institute of Geology, CAGS, Beijing 100037, China 
LI ZhenQing Institute of Mineral Resources, CAGS, Beijing 100037, China 
HU BaoGen Dexing Copper Mine, Jiangxi Copper Co. Ltd., Dexing 334200, Jiangxi, China 
ZHU XiaoYun Dexing Copper Mine, Jiangxi Copper Co. Ltd., Dexing 334200, Jiangxi, China 
WANG ZengKe Dexing Copper Mine, Jiangxi Copper Co. Ltd., Dexing 334200, Jiangxi, China 
YANG Dan Institute of Mineral Resources, CAGS, Beijing 100037, China 
ZHANG TianFu Institute of Geology, CAGS, Beijing 100037, China
China University of Geosciences, Beijing 100083, China 
LI Yan Institute of Geology, CAGS, Beijing 100037, China
China University of Geosciences, Beijing 100083, China 
基金项目:本文由国家科技支撑计划项目"安吉-德兴铜钼多金属矿带成矿规律及勘查模型"(编号: 2011BAB04B02);国土资源部公益性行业科研专项课题"大陆环境斑岩铜金矿床成因模型研究"(编号: 201011011-2)及国家自然科学基金重点项目(编号: 40730419)资助完成
中文摘要:江西铜厂斑岩铜(钼金)矿床是德兴斑岩矿集区最大的矿床。文章根据铜厂矿床发育的钾硅酸盐化、绢英岩化、青磐岩化蚀变组合特征,和已厘定的铜厂矿床脉体类型,选取代表不同蚀变-矿化阶段的石英、黑云母、绢云母及绿泥石等,进行单矿物的H、O同位素测试。石英和黑云母单矿物O同位素,与石英、黑云母平衡流体的δ18O值和δD值联合示踪结果显示,铜厂矿床早期A脉(不规则疙瘩状A1脉、石英-黑云母A2脉和石英-磁铁矿A4脉)和中期B脉(矿物组合为石英-黄铁矿+黄铜矿±辉钼矿±斑铜矿)形成时,成矿热液均为岩浆流体来源,但B脉可能混入了少量大气降水;晚期低温D脉和碳酸岩脉(180~200℃)的成矿热液全部为大气降水来源。斑晶黑云母平衡水的δ18O和δD值变化范围较大表明,黑云母形成时的热液系统主要为岩浆水,局部受区域变质水和大气降水的混染,也可能与少量黑云母斑晶受到后期绿泥石化、水云母化蚀变有关。绿泥石蚀变主要由岩浆流体作用形成,但混入了一些大气降水,导致其δ18O值少量降低。绢云母平衡的水的δ18O值和δD值(4.6‰和-19.4‰)表明,绢云母是大气降水与千枚岩共同作用的结果。总体来说,铜厂矿床钾硅酸盐化、绿泥石化蚀变,以及钾硅酸盐化阶段形成的A脉和B脉,均由岩浆流体作用引起,大气降水在绿泥石化阶段进入蚀变-矿化系统,而绢云母化、晚期低温D脉和碳酸盐脉均是大气降水作用的产物。
中文关键词:地球化学  H-O同位素  成矿热液  斑岩铜(钼金)矿床  铜厂
 
Restriction of H-O isotopes for alteration and mineralization system of Tongchang Cu (-Mo-Au) porphyric deposit, Jiangxi Province
Abstract:Tongchang is the biggest porphyry Cu (Mo, Au) deposit in the Dexing metallogenic ore concentation area. For tracing the origin of ore-forming fluid during complicated mineralization and alteration process of the Tongchang porphyry Cu (-Mo-Au) deposit, the work has been mostly devoted to oxygen isotopes of rocks or spatial anomaly delineation of oxygen isotopes of whole rock, whereas researches on combined hydrogen and oxygen isotopes of single minerals including altered minerals and gauge minerals are very insufficient. According to detailed classification of different alteration and mineralization assemblages, the authors analyzed H and O isotopes of quartz, biotite, chlorite and sericite of different stages in Tongchang porphyry Cu (Mo, Au) deposit to evaluate the source and evolution of the ore-forming fluid. δ18O and δD values of water balanced with quartz and biotite from regular barren quartz veins in phyllite (A1), quartz-biotite veins (A2), quartz-magnetite veins (A4) and quartz-pyrite±chalcopyrite veins(B) show that all the ore-forming fluids were derived from magma except for partial contamination of B-veins by a little meteoric water. δ18O and δD values of quartz from the last low-temperature D-veins and carbonate veins lying at the end of the meteoric water-granodiorite porphyry line indicate that the ore-forming fluid during the last low-temperature stages (180~200℃) were totally derived from meteoric water. Considerable variations of δ18O and δD values of biotite phenocrysts from fresh and chloridie-hydromicazation porphyry suggest that minor amounts of meteoric water and regional metamorphic water were partially involved in the magmatic water during biotite phenocryst crystallization, or late weak chloritization-hydromicazation had already altered granodiorite porphyry. Chloritization was caused by magmatic water besides minor meteoric water, while the sericitization was triggered by the reaction of meteoric water with phyllite. In general, potassium-silicate alteration, chloritization, A-veins and B-veins were formed by the action of magmatic fluid, and meteoric water entered the alteration-mineralization system during chloritization. However, sericitiztion, late low-temperature D-veins and carbonate veins of the Tongchang deposit were formed by meteoric water.
keywords:geochemistry  hydrogen and oxygen isotopes  ore-forming hydrothermal fluid  Cu(-Mo-Au)porphyry deposit  Tongchang
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