内蒙古卓资县大苏计斑岩型钼矿床辉钼矿Re-Os同位素年龄及流体包裹体研究
Received:July 27, 2014  Revised:October 20, 2014  点此下载全文
引用本文:WU Hao,WU Guang,TAO Hong,WANG GuoRui,LI TieGang,CHEN JunQi,YANG NingNing.2014.Molybdenite Re-Os dating and fluid inclusion study of Dasuji porphyry molybdenum deposit in Zhuozi County, central Inner Mongolia[J].Mineral Deposits,33(6):1251~1267
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Author NameAffiliationE-mail
WU Hao School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China
Fourth Detachment of Gold Headquarters, Chinese Armed Police Force, Liaoyang 111000, Liaoning, China 
 
WU Guang MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, CAGS, Beijing 100037, China wuguang65@163.com 
TAO Hong Geophysical Exploration Center of CEA, Zhengzhou 450002, Henan, China  
WANG GuoRui MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, CAGS, Beijing 100037, China  
LI TieGang School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China  
CHEN JunQi Inner Mongolia Zhongxi Mining Limited Liability Company, Ulanqab 012300, Inner Mongolia, China  
YANG NingNing Inner Mongolia Nonferrous Geological Exploration Bureau, Hohhot 010000, Inner Mongolia, China  
基金项目:本文得到内蒙古自治区地质勘查基金项目(编号:201203YS01)和国家自然科学基金项目(编号:41172081)的资助
中文摘要:内蒙古卓资县大苏计钼矿床位于华北克拉通北缘中段的凉城断隆内,是近年来在华北克拉通北缘发现的一个大型斑岩钼矿床,矿体主要产于印支期石英斑岩和正长花岗斑岩中。成矿过程可以划分为石英-钾长石-黄铁矿±辉钼矿±磁铁矿阶段(早阶段)、石英-绢云母-辉钼矿-黄铁矿阶段(中阶段)和石英-方解石-黄铁矿±闪锌矿±方铅矿阶段(晚阶段)。矿石中5件辉钼矿的Re-Os同位素模式年龄介于(223.6±3.1) Ma~(224.2±3.4)Ma之间,其加权平均值为(223.9±1.4)Ma(MSWD=0.017),等时线年龄为(223.5±5.5)Ma(MSWD=0.026),表明大苏计钼矿床形成于印支期。大苏计钼矿床发育富液型、富气型、H2O-CO2型、含子矿物型和纯气相包裹体。成矿早阶段主要发育富液型、富气型包裹体,另有少量H2O-CO2型包裹体,其均一温度介于342~430℃之间,盐度w(NaCleq)介于3.4%~11.0%之间;中阶段主要发育富液型、富气型、H2O-CO2型和含子矿物型包裹体,另有少量纯气相包裹体,其均一温度为234~380℃之间,盐度w(NaCleq)介于6.2%~34.9 %之间;晚阶段仅发育富液型包裹体,其均一温度介于202~280℃之间,盐度w(NaCleq)介于1.2%~11.7%之间,指示该阶段有大气降水的加入。成矿流体从早、中阶段的H2O-NaCl-CO2体系演化为晚阶段的H2O-NaCl体系。早、中阶段流体均为不混溶流体,流体沸腾是成矿物质沉淀的主要机制。集宁地区钼矿床主要为斑岩型,至少存在晚三叠世和晚侏罗世2期钼成矿事件。
中文关键词:地球化学  辉钼矿Re-Os定年  流体包裹体  斑岩型钼矿床  大苏计  内蒙古  华北克拉通北缘
 
Molybdenite Re-Os dating and fluid inclusion study of Dasuji porphyry molybdenum deposit in Zhuozi County, central Inner Mongolia
Abstract:The Dasuji deposit of Inner Mongolia, located in the Liangcheng uplift, is a newly discovered large porphyry Mo deposit in the central segment of the northern margin of the North China Craton. The orebodies of the deposit dominantly occur within the Indosinian quartz porphyry and syenogranite porphyry. The ore-forming process in the deposit can be divided into three stages: the early quartz-potassium feldspar-pyrite±molybdenite±magnetite stage, the middle quartz-sericite-molybdenite-pyrite stage, and the late quartz-carbonate-pyrite±sphalerite±galena stage. Re-Os dating of five molybdenite samples yielded model ages of (223.6±3.1) Ma~(224.2±3.4) Ma, with a weighted mean age of (223.9±1.4) Ma (MSWD=0.017) and an isochron age of (223.5±5.5) Ma (MSWD=0.026), indicating that the Dasuji deposit formed in Indosinian period. Five types of fluid inclusions in quartz veins were recognized, i.e., liquid-rich, gas-rich, H2O-CO2, daughter mineral-bearing, and pure gas inclusions. The fluid inclusions of the early stage are mainly liquid-rich and gas-rich types, with a small amount of H2O-CO2 type; their homogenization temperatures and salinities vary from 342 ℃ to 430 ℃ and from 3.4% to 11.0%, respectively. The inclusions of the middle stage are mainly liquid-rich, gas-rich, H2O-CO2, and daughter minerals-bearing types, with a small amount of pure gas type; these types have homo- genization temperatures and salinities of 234~380 ℃ and 6.2%~34.9%, respectively. The late stage only comprises liquid-rich inclusions with homogenization temperatures and salinities of 202~280 ℃ and 1.2%~11.7%, respectively, indicating that ore-forming fluid of this stage is significantly mixed with meteoric water. The ore-forming fluids evolved from an H2O-NaCl-CO2 system of the early and middle stages to an H2O-NaCl system of the late stage. Both early- and middle-stage fluids are immiscible fluid, and the multi-episode fluid boiling seem to have been the dominant mechanism for mineral deposition. Porphyry Mo deposit is the most important Mo deposit type, and there are at least two periods of porphyry Mo mineralization in the Jining area: late Triassic and late Jurassic.
keywords:geochemistry  molybdenite Re-Os dating  fluid inclusion  porphyry Mo deposit  Dasuji  Inner Mongolia  the northern margin of the North China Craton
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