| 河南老湾金矿床上上河矿段矿床地质和成矿流体地球化学 |
| Received:March 18, 2015 Revised:February 25, 2016 点此下载全文 |
| 引用本文：KOU ShaoLei,DU YangSong,CAO Yi,CHEN JianLi,SHI GeWu,C HEN JinDuo,WANG LiHong.2016.Geology and ore-forming fluid geochemistry of Laowan gold deposit in Tongbai County, Henan Province[J].Mineral Deposits,35(2):245~260 |
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| Author Name | Affiliation | | KOU ShaoLei | School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China | | DU YangSong | School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China | | CAO Yi | School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China | | CHEN JianLi | No. 1 Geological Exploration Institute, Henan Bureau of Geo-exploration and Mineral Development, Zhengzhou 450001, Henan, China | | SHI GeWu | Tongbai Xing Yuan Mining Co., Ltd., Nanyang 474700, Henan, China | | C HEN JinDuo | No. 1 Geological Exploration Institute, Henan Bureau of Geo-exploration and Mineral Development, Zhengzhou 450001, Henan, China | | WANG LiHong | School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China |
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| 基金项目:本文受中国地质调查"河南省桐柏县老湾金矿接替资源勘查(编码:1212011220697)"项目资助 |
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| 中文摘要:河南桐柏老湾金矿床是桐柏-大别山(北坡)金银成矿带内大型造山带型金矿床之一。文章对该矿床的上上河矿段进行了矿床地质和成矿流体地球化学研究,旨在查明该矿段的流体成矿过程。根据矿脉穿插关系、矿石结构构造、矿物共生组合以及黄铁矿的粒度和晶形,将老湾金矿上上河矿段成矿过程划分为:石英粗粒自形黄铁矿(Ⅰ)、石英细粒半自形-他形黄铁矿(Ⅱ)、石英多金属硫化物(Ⅲ)及石英碳酸盐(Ⅳ)4个阶段。镜下观察显示,矿床中的包裹体类型有含CO2包裹体(LH2O+LCO2+VCO2)、纯CO2包裹体(LCO2+VCO2)、液相包裹体(LH2O+VH2O)及少量含子晶包裹体(LH2O+VH2O+S)。第Ⅰ阶段、第Ⅱ阶段和第Ⅲ阶段均可见含CO2包裹体、纯CO2包裹体和液相包裹体,有时可见含CO2包裹体与液相包裹体共存。流体包裹体显微测温结果表明,成矿流体可近似看做中温、低盐度、富CO
2的NaCl-H2O-CO2体系,纯CO2包裹体和液相包裹体所代表的流体可能是由含CO2包裹体所代表的NaCl-H2O-CO2流体经不混溶形成的,三者在寄主矿物沉淀时,被同时捕获而共存。从第Ⅰ阶段到第Ⅳ阶段,成矿流体温度从303~379℃逐渐降低到138~195℃,盐度w(NaCleq)从4.07%~9.59%逐渐降低到1.06%~2.74%。在成矿的第Ⅰ阶段成矿流体发生了不混溶作用,而在第Ⅱ阶段和第Ⅲ阶段流体中的CO2起泡分离再次引发了不混溶作用。从第Ⅰ阶段到第Ⅲ阶段,成矿流体的δ18OH2O从6.56‰~9.71‰经1.89‰~4.01‰变化到0.08‰,δDH2O从-78.1‰~-64.2‰经-79.5‰~-76.3‰变化到-72.6‰,表明老湾金矿第Ⅰ阶段成矿流体主要为岩浆热液,第Ⅱ阶段成矿流体中有少量大气降水加入,第Ⅲ阶段成矿流体中大气降水的比例明显加大。 |
| 中文关键词:地球化学 矿床地质 成矿流体 流体包裹体 不混溶 河南老湾金矿床 |
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| Geology and ore-forming fluid geochemistry of Laowan gold deposit in Tongbai County, Henan Province |
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| Abstract:The Laowan gold deposit, located in Tongbai County of Henan Province, is one of the large orogenic gold deposits on the northern slope of Tongbai-Dabie Mountain gold and silver metallogenic belt. Ore deposit geology and ore-forming fluids geochemistry studies of this deposit were carried out with the purpose of ascertaining its fluid mineralization process. Based on veins cutting relation, ore texture and structure, mineral assemblage, and pyrite size and crystal form, the authors divided fluid mineralization process of the Shangshanghe segment of the Laowan gold deposit into four stages, i.e., stage Ⅰ of quartz with coarse grained euhedral pyrite, stage Ⅱ of quartz with fine grained subhedral-anhedron pyrite, stage Ⅲ of quartz with polymetallic sulfide, and stage Ⅳ of quartz with carbonate. H2O-CO2, pure CO2, and aqueous inclusions were observed under microscopy, with a few aqueous inclusions that contain daughter salt crystals. The H2O-CO2, pure CO2, and aqueous inclusions were always seen in the first, second, and third stages. Coexisting of the H2O-CO2 and the aqueous inclusions could be observed sometimes. Microthermometric data of fluid inclusions indicate that ore-forming fluids were of the NaCl-H2O-CO2 system characterized by middle temperature, low salinity, and CO2 content. The fluids represented by the pure CO2 and aqueous inclusions resulted from an immiscible process of NaCl-H2O-CO2 fluids represented by the H2O-CO2 inclusions. The three types of inclusions were captured at the same time during the host mineral precipitation. Homogenization temperature and salinity of fluid inclusions decreased from 303~379℃ and 4.07%~9.59%NaCl.eq in the first stage to 138~195℃ and 1.06%~2.74%NaCl.eq in the fourth stage, respectively. The first fluid immiscible process occurred in the first stage of the mineralization and the second fluid immiscible process occurred in the second and third stages of mineralization owing to CO2 effervescence of fluids. The values of δ18OH2O and δDH2O changed from -78.1‰~-64.2‰ and 6.56‰~9.71‰ in the first stage through -79.5‰~-76.3‰ and 1.89‰~4.01‰ in the second stage to -72.6‰ and 0.08‰in the third stage, respectively. These isotopic data suggest that the ore-forming fluids were magmatic hydrothermal fluids in the first stage, mixed fluids of magmatic hydrothermal fluid with a small amount of meteoric water in the second stage, and mixed fluids of magmatic hydrothermal fluid with a large amount meteoric water in the third stage. |
| keywords:geochemistry ore geology ore-forming fluid fluid inclusions immiscibility Laowan gold deposit in Henan Province |
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