江南钨矿带高家塝钨多金属矿床矿化分带特征及其指示意义
Received:October 22, 2020  Revised:February 28, 2021  点此下载全文
引用本文:REN KangDa,ZHANG DaYu,YE LongXiang,MENG Xiang,YI Hong,HUANG JiaLong,WAN ShuWen,ZHOU TaoFa.2021.Metallogenic zonation of Gaojiabang tungsten polymetallic deposit in Jiangnan tungsten ore belt and its significance[J].Mineral Deposits,40(2):369~383
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Author NameAffiliationE-mail
REN KangDa School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, Anhui, China  
ZHANG DaYu School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, Anhui, China dayuzhang@hfut.edu.cn 
YE LongXiang School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, Anhui, China  
MENG Xiang School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, Anhui, China  
YI Hong No. 812 Geological Party, East China Metallurgical Geological Survey Bureau, Tongling 244008, Anhui, China  
HUANG JiaLong Institute of Geological Exploration, East China Metallurgical Geological Survey Bureau, Hefei 230088, Anhui, China  
WAN ShuWen School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, Anhui, China  
ZHOU TaoFa School of Resources and Environmental Engineering, Hefei University of Technology, Hefei 230009, Anhui, China  
基金项目:本文得到国家自然科学基金项目(编号:41972076、91962218)、科技部深地资源勘查开采专项(编号:2016YFC0600206)和安徽省自然资源科技项目(编号:2020-K-11)联合资助
中文摘要:高家塝钨多金属矿床位于江南钨矿带北部。钨矿化发育在花岗闪长斑岩与黄柏岭组接触的矽卡岩及其两侧。从岩体向外将矿石划分为:花岗闪长斑岩中细脉浸染状白钨矿矿石(类型Ⅰ)、矽卡岩中浸染状白钨矿矿石(类型Ⅱ)、角岩中脉状白钨矿矿石(类型Ⅲ)3类。高家塝矿床不同类型矿石的白钨矿和磁黄铁矿电子探针(EPMA)分析结果显示,白钨矿w(Mo)从类型Ⅱ(w(Mo)=1.34%~1.40%)→类型Ⅲ(w(Mo)=0.01%~0.17%)→类型Ⅰ(w(Mo) < 0.01%)降低。从类型Ⅰ→类型Ⅱ→类型Ⅲ,磁黄铁矿中Cu、Fe元素含量降低;Zn、Co、Ni含量增高。高家塝钨矿床形成白钨矿的成矿流体从类型Ⅱ→类型Ⅲ→类型Ⅰ,氧逸度降低;形成磁黄铁矿的早期石英-硫化物阶段,类型Ⅱ的成矿流体降温速率缓慢,类型Ⅰ和Ⅲ的成矿流体发生快速冷凝作用。区域对比研究显示,高家塝矿床为贫钼白钨矿矿床,形成于还原环境。
中文关键词:地球化学  白钨矿  磁黄铁矿  EPMA  成矿指示  江南钨矿带
 
Metallogenic zonation of Gaojiabang tungsten polymetallic deposit in Jiangnan tungsten ore belt and its significance
Abstract:The Gaojiabang tungsten polymetallic deposit is located in the northern sector of the Jiangnan tungsten ore belt. Tungsten mineralization occurs in the skarn and its adjacent parts between granodiorite porphyry and Huangbailing Formation. According to the spatial location and modes of occurrence, the ores can be subdivided into three types:scheelite in porphyry (type Ⅰ), scheelite in skarn (type Ⅱ) and scheelite in hornblende (type Ⅲ). The EPMA analysis results show that Mo content in the scheelite grains decreases from type Ⅱ ore (w(Mo)=1.34%~1.40%) through type Ⅲ ore (w(Mo)=0.01%~0.17%) to type Ⅰ ore (w(Mo) < 0.01%). The values of Cu and Fe in pyrrhotite grains gradually decrease, while the values of Zn, Co and Ni gradually increase from type Ⅰ ore through type Ⅱ ore to type Ⅲ ore. This metallogenic zonation indicates that, in the Gaojiabang tungsten polymetallic deposit, the oxygen fugacity of ore-forming fluid in skarn-stage gradually decreased from type Ⅱ ore through type Ⅰ ore to type Ⅲ ore, and in quartz sulfide stage, the cooling rate of ore-forming fluid that formed type Ⅱ ore was much higher than that of type Ⅰ and type Ⅲ ores. A comparison with regional tungsten polymetallic deposits shows that the Gaojiabang deposit is a Mo-poor scheelite deposit, which was formed in a relatively reduced metallogenic system.
keywords:geochemistry  scheelite  pyrrhotite  EPMA  metallogenic indicator  Jiangnan tungsten ore belt
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